MB3P2S10 (M = Rb, Cs): two new alkali metal thioboratephosphates with [B6P4S20] T3-supertetrahedra.

Authors :: Zhou, Jiazheng
Su, Xin
Luo, Ling
Li, Junjie
Yu, Feng
Source :: Dalton Transactions: An International Journal of Inorganic Chemistry. 9/7/2023, Vol. 52 Issue 33, p11401-11406. 6p.
Publication Year :: 2023
Abstract: Two new alkaline metal thioboratephosphates, RbB3P2S10 and CsB3P2S10, have been designed and fabricated by the flux method. The two compounds are composed of alkali metal polyhedral and [B6P4S20] T3-supertetrahedral units, and crystallize in I41/a and R3¯c space groups, respectively. The results enrich the chemical diversity of chalcogenides, and give insights for the exploration of new functional materials in thioboratephosphates. [ABSTRACT FROM AUTHOR]

Language :: English
ISSN :: 14779226
Volume :: 52
Issue :: 33
Database :: Academic Search Index
Journal :: Dalton Transactions: An International Journal of Inorganic Chemistry
Publication Type :: Academic Journal
Accession number :: 170047639
Full Text :: https://doi.org/10.1039/d3dt01496g

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