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A squaramide cage capable of binding and extracting H2PO4− and HP2O73− in highly polar protic media.
- Source :
-
Chemical Communications . 8/25/2023, Vol. 59 Issue 66, p9988-9991. 4p. - Publication Year :
- 2023
-
Abstract
- A novel squaramide cage (2) binds H2PO4− and HP2O73− with high selectivity and affinity in a highly polar protic solvent system. Receptor 2 is also able to extract these hydrophilic anions into a chloroform phase from water. The X-ray crystal structure demonstrated that compound 2 forms a complex with H2PO4− with 1 : 1 stoichiometry in the solid state. [ABSTRACT FROM AUTHOR]
- Subjects :
- *PROTOGENIC solvents
*POLAR solvents
*CRYSTAL structure
*STOICHIOMETRY
*CHLOROFORM
Subjects
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 59
- Issue :
- 66
- Database :
- Academic Search Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 169952215
- Full Text :
- https://doi.org/10.1039/d3cc02611f