On the potential of cool materials in the urban heat island context: Scalability challenges and technological setbacks towards building decarbonization.

[Display omitted] • A total of 95 papers systematically reviewed cool material as a mitigation strategy for urban heat island (UHI). • Based on the type of reflection and the spectral range, the analysis found 7 material technologies (UV–Vis-NIR). • Optical properties such as reflectance (ρ), absorptance (α), and emittance (ε) are key factors in cool materials design. • Technological setbacks constitute a key limitation to scale cool material technologies and low-cost alternatives. • DRC and super cool materials represent the most efficient innovations amongst current technologies. The challenging urban expansion represents a pressing need to implement climate mitigation strategies for the urban heat island (UHI) effects and significant threats to the environmental quality, energy consumption, and human health. Thus, this manuscript systematically evaluates 95 relevant studies through a robust evidence-based analysis centered on the latest advances in cool materials, their potential, technological innovation, and global trends. The results showed studies in 21 countries, 81 cities, and 16 climate zones, of which the majority belong to Humid subtropical climates (Csa) including 29 % of studies, Oceanic climates (Cfb) with 15 %, and Mediterranean climates (Cfa) with 13 %. Spectrophotometry analysis is used in 48 % of the studies, while the most studied technologies are the Daytime Radiative Cooling (DRC); 22 %, followed by Thermochromics (TC); 19 %, Cool-Colored (CC); 17 %, Phase Change Materials (PCM); 17 %, Retroreflectives (RR); 11 %, Light-colored (LC); 5 % and Fluorescents (FL); 5 %. Finally, DRC reported the highest cooling power of up to 136 W/m2, however, the latest developments advocate for climate-dependent dynamic modulation techniques of Super Cool Materials (SCM) with Passive Daytime Radiative Cooling (PDRC) attributes and engineered spectral properties to dissipate urban heat to outer space in different meteorological conditions and wavelengths levels of the atmospheric window (8–13 μm). [ABSTRACT FROM AUTHOR]