Back to Search
Start Over
Mineralogical and microstructural studies of C–S–H exposed to sulphate attack.
- Source :
-
European Journal of Environmental & Civil Engineering . Sep2023, Vol. 27 Issue 11, p3489-3506. 18p. - Publication Year :
- 2023
-
Abstract
- Calcium–silicate–hydrate (C–S–H), the most important phase of hydrated portland cement, is responsible for the cementitious system's mechanical properties performance and durability. In a severe environment, C–S–H often suffers from sulphate attack, leading to severe concrete deterioration. The present work describes a detailed mechanism of sulphate attack on C–S–H from 28 to 270 days of sulphate curing (10% Na2SO4 solution) using XRD, TGA, FTIR, 29Si-NMR and FESEM/EDX techniques. The results show that gypsum is the only sulphate-bearing product formed by decalcification of calcium hydroxide first and then of C–S–H. Decalcification enhances polymerization in the C–S–H structure as an additional Q3 peak was observed in FTIR and 29Si-NMR analysis. The microstructure of C–S–H becomes more crystalline as the sulphate curing period increases, as observed in FESEM micrographs. In addition, sulphate adsorption on C–S–H was identified through FESEM/EDX, which could play an important role in the deterioration of cementitious materials. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 19648189
- Volume :
- 27
- Issue :
- 11
- Database :
- Academic Search Index
- Journal :
- European Journal of Environmental & Civil Engineering
- Publication Type :
- Academic Journal
- Accession number :
- 169922569
- Full Text :
- https://doi.org/10.1080/19648189.2022.2140206