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Spin crossover in mixed-anion Fe(NH2trz)3(BF4)(SiF6)0.5 crystalline rod-shaped particles: the strength of the solid–liquid post synthetic modification.
- Source :
-
Dalton Transactions: An International Journal of Inorganic Chemistry . 8/21/2023, Vol. 52 Issue 31, p10828-10834. 7p. - Publication Year :
- 2023
-
Abstract
- A pure mixed-anion Fe(NH2trz)3(BF4)(SiF6)0.5 spin crossover complex is obtained implementing a solid–liquid post synthetic modification approach from the Fe(NH2trz)3(BF4)2 parent complex. This method allows obtaining highly crystalline powder samples incorporating homogeneous micrometric (1 μm long) rod-shaped particles. This compound presents an abrupt spin crossover behaviour with a narrow (10 K) hysteresis loop centred just above room temperature (320 K) which makes it very interesting for future integration into devices for various applications. [ABSTRACT FROM AUTHOR]
- Subjects :
- *SPIN crossover
*FERRIMAGNETIC materials
*HYSTERESIS loop
Subjects
Details
- Language :
- English
- ISSN :
- 14779226
- Volume :
- 52
- Issue :
- 31
- Database :
- Academic Search Index
- Journal :
- Dalton Transactions: An International Journal of Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 169813864
- Full Text :
- https://doi.org/10.1039/d3dt02003g