Combination of electrochemically activated persulfate process and electro-coagulation for the treatment of municipal landfill leachate with low biodegradability.

To handle complex wastewater with limited biodegradability, hybrid treatment systems are necessary. The current study represents the combined effectiveness of sulfate-radical associated electro-chemical advanced oxidation process (SR-EAOP) and electro-coagulation (EC) for the treatment of stabilized landfill leachate. For SR-EAOP, Pt/Ti was employed as the anode and an iron plate as the cathode; while EC treatment was performed by switching the polarity. Hence, both electrochemical treatment was carried out in single reactor. Initially, the effects of pH, applied voltage, persulfate and Fe2+ dosage, on the performance of SR-EAOP was examined. Sulfate radical was generated in the electrolytic system via cathodic reduction of persulfate (PS) and ferrous (Fe2+) ion activation. Auxiliary processes such as anodic oxidation via Pt/Ti anode and indirect electro-chemical oxidation were also contributed for pollutant degradation. Combined process SR-EAOP followed by EC (SR-EAOP + EC) has better leachate treatment efficacy in comparison with EC + SR-EAOPs. The SR-EAOP + EC based combined treatment mechanism achieved an efficient COD reduction of 88.67% than that of EC + SR – EAOP process (74.51% COD reduction). Characterization studies have been carried out for post-treated dried-sludge using Field Emission scanning electron microscope (FE-SEM) and X-ray powder diffraction (XRD) techniques. The combined process treatment (SR-EAOP + EC) can be applied as pre-treatment for leachate decontamination. [Display omitted] • SR-EAOP + EC process is found effective for the treatment of landfill leachate. • Performance of SR-EAOP + EC process is much better than EC + SR-EAOP process. • Biodegradability of landfill leachate increased from 0.195 to 0.57 after the treatment. • SR-EAOP + EC can be applied as pre-treatment for landfill leachate. [ABSTRACT FROM AUTHOR]