Mechanical crystallization induced Sm3+-doped CsPbBr3 quantum dots glass for high-sensitivity temperature sensing.

The traditional preparation methods of quantum dots (QDs) for temperature sensing are limited to self-crystallization and secondary heat treatment processes, which requires precise control of the experimental equipment and conditions. In this paper, CsPbBr 3 QDs are successfully obtained by friction crystallization in the prepared precursor glass. The results show that when the glass network structure is subjected to continuous mechanical impact, the thermal kinetic energy of the fracture surface increases. Therefore, the combination of relatively loose structure and local thermal energy supply more excellent space for the nucleation and growth of CsPbBr 3 QDs. Furthermore, the PL enhancement is confirmed to be occur in Sm3+ ions doped CsPbBr 3 QDs, which is due to the increase of density of exciton states near the edge of the band, thus facilitating radiative recombination. Significantly, this material has a favorable performance of temperature sensing and thermal stability, with the maximum relative sensitivity of 3.09 % K−1. This work provides an energy-saving and green way for the preparation of Sm3+ ions doped QDs, and the materials provide potential applications in the field of temperature sensing. • Sm3+ ions doped CsPbBr 3 quantum dot glass are successfully prepared by mechanical crystallization method. • The loose structure is conducive to ions migration and recombination, thus promoting crystallization. • The material shows good thermal stability and temperature sensing performance, with a Sr of 3.09 % K -1. [ABSTRACT FROM AUTHOR]