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Slip to π Ru: structural distortions due to metal-iminoxolene π bonding.
- Source :
-
Chemical Communications . 8/14/2023, Vol. 59 Issue 63, p9618-9621. 4p. - Publication Year :
- 2023
-
Abstract
- Both pseudo-octahedral and pseudo-square pyramidal bis-iminoxolene complexes trans-(Diso)2RuCl2 and trans-(Diso)2Ru(PPh3) are structurally distorted, with the ruthenium atom slipping off the twofold axis of the idealized coordination polyhedra. These distortions take place because they allow or enhance π interactions between ruthenium and the iminoxolene π orbitals. [ABSTRACT FROM AUTHOR]
- Subjects :
- *RUTHENIUM
*POLYHEDRA
*ATOMS
Subjects
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 59
- Issue :
- 63
- Database :
- Academic Search Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 169750176
- Full Text :
- https://doi.org/10.1039/d3cc02943c