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Preparation of Pt–Ru bimetallic anodes by galvanostatic pulse electrodeposition: characterization and application to the direct methanol fuel cell.
- Source :
-
Journal of Applied Electrochemistry . Jan2004, Vol. 34 Issue 1, p61-66. 6p. - Publication Year :
- 2004
-
Abstract
- The electrodeposition of platinum and ruthenium was carried out on carbon electrodes to prepare methanol anodes with different Pt/Ru atomic ratios using a galvanostatic pulse technique. Characterizations by XRD, TEM, EDX and atomic absorption spectroscopy indicated that most of the electrocatalytic anodes consisted of 2 mg cm-2 of Pt–Ru alloy particles with the desired composition and with particle sizes ranging from 5 to 8 nm. Electrochemical tests in a single DMFC show that these electrodes are very active for methanol oxidation and that the best Pt/Ru atomic ratio in the temperature range used (50–110 °C) is 80:20. The influence of the relaxation time toff was also studied and it appeared that a low toff led to smaller particle sizes and higher performances in terms of current density and power density. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 0021891X
- Volume :
- 34
- Issue :
- 1
- Database :
- Academic Search Index
- Journal :
- Journal of Applied Electrochemistry
- Publication Type :
- Academic Journal
- Accession number :
- 16781877
- Full Text :
- https://doi.org/10.1023/B:JACH.0000005578.83646.3a