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Synthesis and Optical Properties of π-Conjugated Azulenes.
- Source :
-
Russian Journal of Organic Chemistry . May2023, Vol. 59 Issue 5, p782-786. 5p. - Publication Year :
- 2023
-
Abstract
- The Knoevenagel condensation of azulenyl ketones with malononitrile resulted in the synthesis of π-conjugated 1-mono- and 1,3-bis(phenyldicyanovinyl)azulenes, and the Kumada cross-coupling reaction of bromazulenes with PhMgBr gave 1-mono- and 1,3-biphenylazulene. The electronic spectra of dicyanovinylated azulenes showed strong absorption bands of intramolecular charge transfer in the visible region, as well as significant bathochromic shifts of the absorption maxima of phenylazulenes. [ABSTRACT FROM AUTHOR]
- Subjects :
- *INTRAMOLECULAR charge transfer
*OPTICAL properties
*ELECTRONIC spectra
Subjects
Details
- Language :
- English
- ISSN :
- 10704280
- Volume :
- 59
- Issue :
- 5
- Database :
- Academic Search Index
- Journal :
- Russian Journal of Organic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 166105497
- Full Text :
- https://doi.org/10.1134/S1070428023050068