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Keggin polyoxometalate with pendant tricyclic, aromatic entity
- Source :
-
Journal of Molecular Structure . Mar2005, Vol. 738 Issue 1-3, p1-7. 7p. - Publication Year :
- 2005
-
Abstract
- Abstract: A Keggin polyoxometalate with pendant tricyclic, aromatic entity, formulated as (Hpbpy)5[PW11O39Co(pbpy)]·2H2O (1) (pbpy=5-phenyl-2-(4-pyridinyl)pyridine), was synthesized and characterized by X-ray single crystal structure analysis and temperature-dependent magnetic susceptibility, which represents an unprecedented organic capped-structure. Crystal data: C96H81N12O41PCoW11, triclinic, P-1, a=14.352(3)Å, b=20.467(4)Å, c=21.141(4)Å, α=61.30(3)°, β=75.87(3)°, γ=88.63(3)°, V=5250.5(18)Å3, Z=2. [Copyright &y& Elsevier]
- Subjects :
- *POLYOXOMETALATES
*AROMATIC compounds
*X-rays
*MAGNETIC susceptibility
Subjects
Details
- Language :
- English
- ISSN :
- 00222860
- Volume :
- 738
- Issue :
- 1-3
- Database :
- Academic Search Index
- Journal :
- Journal of Molecular Structure
- Publication Type :
- Academic Journal
- Accession number :
- 16596895
- Full Text :
- https://doi.org/10.1016/j.molstruc.2004.07.004