Fe-Co/Fe3C dual active sites catalysts supported on nitrogen-doped graphitic carbon for ultrafast degradation of high concentration Rhodamine B.

Iron-based catalysts have garnered great attention as alternatives for Fenton-like catalysts in the degradation of organic compounds. However, there is a demand for the synthesis of highly efficient iron-based catalysts that can solve the problems of iron dissolution and poor stability. Herein, nitrogen-doped graphitic carbon-supported Fe-Co/Fe 3 C dual active sites catalyst (Fe-Co/Fe 3 C-NC) is successfully prepared by ball milling method combined with subsequent high-temperature self-reduction. 0.5 wt%-Fe-Co/Fe 3 C-NC shows high efficiency in the activation of peroxymonosulfate (PMS) for the ultrafast degradation of high concentration Rhodamine B (200 mg/L of RhB is completely degraded within 8 min and the degradation rate constant is as high as 0.5066 min−1), as well as high stability and good reproducibility, attributing to the synergistic mechanism between the dual active sites (Fe-Co and Fe 3 C) and the adsorption sites (Fe 3 C and pyrrolic-N). Chemical quenching experiments and electron paramagnetic resonance indicate that the prepared 0.5 wt%-Fe-Co/Fe 3 C-NC exhibits outstanding activation for PMS by generating reactive oxygen species (SO 4 •−, •OH, 1O 2) and high-valent FeCo=O species. This work shows useful insights into the synthesis of iron-based dual active sites catalysts, providing exciting chances for the highly efficient degradation of high concentration organic wastewater. [Display omitted] • Successful synthesis of Fe-Co/Fe 3 C-NC using ball milling method combined with high-temperature self-reduction. • Fe-Co/Fe 3 C-NC shows high efficiency and stability in the activation of PMS for the degradation of RhB. • The superior degradation performance is attributed to the synergistic effect between the active and adsorption sites. • The outstanding activation of Fe-Co/Fe 3 C-NC for PMS ascribes SO 4 •− and 1O 2 species and high-valent FeCo=O. [ABSTRACT FROM AUTHOR]