Solid-State Silver-Catalyzed Ring-Opening Fluorination of Cyclobutanols by Using Mechanochemistry.

Although the benefits of mechanochemistry for solid-state reactions of compounds with reactive bonds, such as organic halides, have been well demonstrated, nonactivated bond cleavage through mechanochemical transformation remains unexplored. Keywords: C-C bond cleavage; fluorination; mechanochemistry; ball-milling; solid-state chemistry; silver catalysis EN C-C bond cleavage fluorination mechanochemistry ball-milling solid-state chemistry silver catalysis 1419 1424 6 07/11/23 20230725 NES 230725 Graph In recent years, solvent-free solid-state organic transformations using ball-milling, known as mechanochemical reactions, have been extensively studied as new tools for organic chemistry. C-C bond cleavage, fluorination, mechanochemistry, ball-milling, silver catalysis, solid-state chemistry. [Extracted from the article]