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Electron‐Driven Nitration of Unsaturated Hydrocarbons.
- Source :
-
Angewandte Chemie International Edition . 7/10/2023, Vol. 62 Issue 28, p1-10. 10p. - Publication Year :
- 2023
-
Abstract
- Herein, we introduce an electrochemically assisted generation of nitryl radicals from ferric nitrate under mild reaction conditions using a simple setup with inexpensive graphite and stainless‐steel electrodes. The mechanism of the reaction is supported by detailed spectroscopic and experimental studies. Powered by electricity and driven by electrons, the synthetic diversity of this reaction has been demonstrated through the development of highly efficient nitration protocols of various unsaturated hydrocarbons. In addition to a broad application area, these protocols are easy to scale for decagram quantities, and exhibit exceptional substrate generality and functional‐group compatibility. [ABSTRACT FROM AUTHOR]
- Subjects :
- *NITRATION
*FERRIC nitrate
*HYDROCARBONS
*RADICALS (Chemistry)
*GRAPHITE
Subjects
Details
- Language :
- English
- ISSN :
- 14337851
- Volume :
- 62
- Issue :
- 28
- Database :
- Academic Search Index
- Journal :
- Angewandte Chemie International Edition
- Publication Type :
- Academic Journal
- Accession number :
- 164682737
- Full Text :
- https://doi.org/10.1002/anie.202300533