Three-dimensional urchin-like N/S co-doped Mn-based metal-organic frameworks for efficiently enabling oxygen reduction reaction.

The exploration of economical and effective non-noble metal catalysts is essential for oxygen reduction reaction (ORR) in energy devices. Recently, heteroatom-doped metal-organic frameworks (MOFs) have shown great potential in ORR due to their high efficiencies and low costs. Herein, three-dimensional (3D) urchin-like N/S co-doped Mn-based MOFs (U–N/S–Mn-MOFs) as an effective ORR catalyst have been successfully prepared by a facile one-step solvothermal methodology. The unique 3D urchin-like structure with a spherical interior and dendritic exterior may provide more catalytic sites and transport channels for ORR. Simultaneously, the doped N and S combined with Mn can promote oxygen adsorption and reduce the reaction energy barrier. These characteristics endow U–N/S–Mn-MOFs with high ORR performance. The present work provides a new opportunity for multiple heteroatom-doped MOFs to achieve high electrocatalytic performance. • U–N/S–Mn-MOFs have been prepared by a facile one-pot solvothermal methodology. • The impact factors of the prepared MOFs are investigated in detail. • U–N/S–Mn-MOFs exhibit high ORR performance in alkaline medium. • The unique 3D urchin-like structure and N/S codoping ensure high ORR performance. [ABSTRACT FROM AUTHOR]