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Synthesis and Structure of Cu(II) and Co(II) Complexes with N-{2-[(E)-(4-Cyclohexylphenyl)Iminomethyl]Phenyl}-4-Methylbenzene-1-Sulfonamide.

Authors :
Vlasenko, V. G.
Burlov, A. S.
Kiskin, M. A.
Nikolaevsky, S. A.
Koshchienko, Yu. V.
Shiryaeva, A. A.
Source :
Journal of Structural Chemistry. May2023, Vol. 64 Issue 5, p906-916. 11p.
Publication Year :
2023

Abstract

New Cu(II) and Co(II) complexes with the N-{2-[(E)-(4-cyclohexylphenyl)iminomethyl]phenyl}-4-methylbenzene-1-sulfonamide Schiff base are prepared and characterized by 1H NMR, IR spectroscopy, and elemental analysis. The crystal structure of azomethine and its complexes is studied by XRD. The obtained XRD data show that two N,N-bidentate ligands are chelated to Cu(II) and Co(II) ions in both complexes and form a distorted tetrahedral environment of four nitrogen atoms around the ions. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
00224766
Volume :
64
Issue :
5
Database :
Academic Search Index
Journal :
Journal of Structural Chemistry
Publication Type :
Academic Journal
Accession number :
163990434
Full Text :
https://doi.org/10.1134/S0022476623050098