Improving the chronostratigraphic framework of the Transvaal Supergroup (South Africa) through in-situ and high-precision U-Pb geochronology.

• Combination of dating techniques improves accuracy of determination. • Spurious detrital zircon dates post-dating crystallization found by LA-ICP-MS. • LA-ICP-MS studies should routinely chemically abrade zircon prior to analyses. • The oldest Paleoproterozoic glacial event is dated to 2423.1 ± 1.0 Ma. • Anoxic atmospheric settings from the Koegas Subgroup are dated to 2451.5 ± 2.5 Ma. The Transvaal Supergroup, on the Kaapvaal Craton in South Africa, is widely accepted as one of the best-preserved sedimentary archives to constrain planetary-scale environmental changes during the late Archean and early Proterozoic, yet the sedimentation age for certain stratigraphic intervals remains poorly constrained. To improve the temporal control on some of the first-order global changes recorded in these rocks, we carried out U-Pb analyses of detrital zircon populations from several clastic and volcano-clastic sedimentary units of the Transvaal Supergroup. We applied the Chemical Abrasion-Isotope Dilution-Thermal Ionization Mass Spectrometry (CA-ID-TIMS) technique on detrital and volcanic zircon populations that had been previously screened using the Laser Ablation-Inductively Coupled Plasma-Mass Spectrometry (LA-ICP-MS) technique. We report new maximum depositional age estimates for the Pannetjie (2456.6 ± 7.0 Ma), the Heynskop (2451.5 ± 2.5 Ma), the Makganyene (2423.1 ± 1.0 Ma) and the Hekpoort formations (2248.0 ± 1.1 Ma). A ca. 2.25 Ga-old cluster of LA-ICP-MS analyses in the Makganyene Formation was identified to be spurious, since it was completely removed during the chemical abrasion. Thus, we speculate that circulation of hydrothermal fluids and associated Pb-loss from a radiation-damaged lattice during the emplacement of the much younger Hekpoort Formation or possibly the Ophthalmia Orogeny, recorded in Western Australia, may have reset the U-Pb system of this zircon population. This implies that the accurate maximum depositional age of the Makganyene Formation is ca. 2.42 Ga instead, which denotes the age of the oldest glacial event of global extent during the Paleoproterozoic. Therefore, we suggest that the combination of both dating techniques is essential to ensure accurate maximum depositional age constraints for ancient detrital sedimentary rocks. Additionally, our data provides temporal constraints on a period characterized by major fluctuations in atmospheric oxygen. Finally, and supporting the complex nature of the Paleoproterozoic, linkages between widespread glaciations and atmospheric oxygen fluctuations remain to be explored. [ABSTRACT FROM AUTHOR]