Particle travel rates and the enrichment of carbon in the sediment discharged by rain-impacted flows.

• Demonstration of rise and fall of carbon discharge with time. • Demonstration of enrichment of sand in loose layer above soil. • Demonstration of no carbon enrichment is sediment at the steady state. Soil carbon losses from sheet and interrill erosion areas have an impact on the global carbon cycle. Sediment discharged in many experiments where artificial rainfall has been applied to sloping soil surfaces show greater proportions of carbon in the sediment than found in the cohesive soil source. In many cases, conclusions drawn from these experiments fail to recognise that the enrichment of carbon in the sediment discharge is a result of unsteady conditions that occur before the steady state develops. It is known that particles of sand of different sizes move at different rates when raindrop induced salation occurs with the result that initially the particle size distribution is finer than the source but tends towards that of the source as time progresses. The presence of carbon in aggregates influences the density of aggregates. Here a qualitative model of sediment transport of sand and coal particles by raindrop induced saltation is used to demonstrate time varying enrichment of coal resulting from the effect of carbon on particle settling velocity. The model also demonstrates how the layer of loose particles that develops on top of the cohesive soil surface influences the relative amounts of carbon and sand in the sediment discharges. The steady state is not achieved until the slowest moving particle detached at the farthest distance from the downslope boundary is discharged. That may not be achieved in many of the experiments reported in the literature. [ABSTRACT FROM AUTHOR]