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Tri(2-furyl)phosphine-induced robust interphases for durable Nickel-rich Lithium-ion batteries.
- Source :
-
Applied Surface Science . Jul2023, Vol. 624, pN.PAG-N.PAG. 1p. - Publication Year :
- 2023
-
Abstract
- [Display omitted] • FuP was first used as an electrolyte additive to stabilize NCM811/Gr. • NCM811/Gr cell with FuP delivers 90% capacity retention after 600 cycles. • The stable SEI films induced by FuP decrease the polarization and impedance of cell. • FuP can induce the formation of stable LiF, Li x PO y F z , and additional OP species. • FuP protects both the cathode and anode by forming robust SEI films. Ni-rich LiNi x Co y Mn 1−x−y O 2 /graphite batteries with Ni ≥ 0.8 have aroused great interest in high-energy–density Li-ion batteries. However, their practical applications still face huge challenges owing to severe capacity fading on unstable cathodic solid electrolyte interfaces (SEI). Herein, we propose an advanced electrolyte additive, tri(2-furyl)phosphine (FuP), to induce the simultaneous formation of robust SEI films on cathode and anode surfaces. This interphase can significantly improve the cyclability of commercial LiNi 0.8 Co 0.1 Mn 0.1 O 2 /graphite pouch cells at 45 °C and reduce cell impedance during cycling. The capacity retention rate of the cells with the FuP-based electrolyte can reach 90 % after 600 cycles, which is considerably better than that of baseline batteries (70 %). Mechanistic studies indicate that FuP suppresses the formation of fragile Li 2 CO 3 to generate more stable LiF, Li x PO y F z , and additional organic phosphorus species on the electrode surface, thereby preventing cation disorder and irreversible phase transitions. These results provide a facile and efficient strategy for enhancing the performance of Ni-rich Li-ion batteries. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 01694332
- Volume :
- 624
- Database :
- Academic Search Index
- Journal :
- Applied Surface Science
- Publication Type :
- Academic Journal
- Accession number :
- 163164024
- Full Text :
- https://doi.org/10.1016/j.apsusc.2023.157027