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Anion Modulated Expression of Chirality in Hydrogen Bond Templated Mechanically Chiral [2]Rotaxanes.
- Source :
-
Chemistry - A European Journal . 4/13/2023, Vol. 29 Issue 21, p1-8. 8p. - Publication Year :
- 2023
-
Abstract
- The syntheses of two novel mechanically chiral rotaxanes containing urea and squaramide motifs (in yields of 33 % and 22 %, respectively) are presented. 1H NMR spectroscopic titrations reveal shuttling of the macrocycle – detectable by modulation of the expression of mechanical chirality in the NMR spectrum – is possible through the addition of achiral chloride anions, a process which is reversed by the addition of sodium cations. [ABSTRACT FROM AUTHOR]
- Subjects :
- *HYDROGEN bonding
*CHIRALITY
*ROTAXANES
*ANIONS
*SUPRAMOLECULAR chemistry
Subjects
Details
- Language :
- English
- ISSN :
- 09476539
- Volume :
- 29
- Issue :
- 21
- Database :
- Academic Search Index
- Journal :
- Chemistry - A European Journal
- Publication Type :
- Academic Journal
- Accession number :
- 163098411
- Full Text :
- https://doi.org/10.1002/chem.202203502