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An approach for upgrading behavior and bio-oil production using CO2-assisted cellulose pyrolysis in cobalt-based Ce/Fe/Mg composite catalyst.
- Source :
-
Fuel . Jul2023, Vol. 344, pN.PAG-N.PAG. 1p. - Publication Year :
- 2023
-
Abstract
- • Catalysts that can effectively promote cellulose decomposition are synthesized. • CO 2 -assisted cobalt-based Ce/Fe/Mg catalyst enhances furans and ketones. • The synthesized catalyst has good oxygen transfer ability. • The performance of catalyst in improving the selectivity of compound is given. The production of high value-added liquid products by catalytic pyrolysis of cellulose has become an effective way to realize the efficient utilization of biomass. This work synthesized a series of Co-Ce, Co-Fe and Co-Mg composite metal catalysts and used them to obtain furans and ketones production. In addition, the CO 2 was used as a pyrolysis atmosphere to investigate the synergistic effect between CO 2 and the prepared catalyst. The results showed that the catalyst effectively promoted the depolymerization of cellulose and improved the oxygen transfer behavior between volatile matters during cellulose pyrolysis. As a reaction medium, CO 2 influenced the carbon distribution of products, thereby increasing syngas yield, and the CO 2 atmosphere promoted the formation of furans and ketones. Compared with those obtained by the non-catalytic pyrolysis in N 2 atmosphere, the relative contents of furans and ketones in the liquid products produced by the catalytic pyrolysis of cellulose in CO 2 atmosphere increased by about 13.38% and 9.8%. In the CO 2 environment, the generation ability for furans was Co-Mg catalyst > Co-Ce catalyst > Co-Fe catalyst, and the generation ability for ketones was Co-Ce catalyst > Co-Mg catalyst > Co-Fe catalyst. These works provide an important way for the efficient preparation of furans and ketones from biomass pyrolysis. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00162361
- Volume :
- 344
- Database :
- Academic Search Index
- Journal :
- Fuel
- Publication Type :
- Academic Journal
- Accession number :
- 162979403
- Full Text :
- https://doi.org/10.1016/j.fuel.2023.128129