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rac-1-(4-tert-Butylphenyl)-5-ethyl-4-ferrocenyl-5-hydroxy-1H-pyrrol-2(5H)-one.

Authors :
Biletzki, Tobias
Görls, Helmar
Imhof, Wolfgang
Source :
Acta Crystallographica Section E: Crystallographic Communications. Mar2023, Vol. 79 Issue 4, p264-266. 12p.
Publication Year :
2023

Abstract

The title compound, [Fe(C5H5)(C21H24NO2)], which is produced by the oxidation of 1-(4-tert-butylphenyl)-2-ethyl-3-ferrocenylpyrrole, crystallizes as a racemic mixture in the centrosymmetric space group P21/n. The central heterocyclic pyrrole ring system subtends dihedral angles of 13.7 (2)° with respect to the attached cyclopentadienyl ring and of 43.6 (7)° with the major component of the disordered phenyl group bound to the N atom. The 4-tertbutylphenyl group, as well as the non-substituted Cp ring are disordered with s.o.f. values of 0.589 (16) and 0.411 (16), respectively. In the crystal, molecules with the same absolute configuration are linked into infinite chains along the baxis direction by O--H· · ·O hydrogen bonds between the hydroxy substituent and the carbonyl O atom of the adjacent molecule. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
20569890
Volume :
79
Issue :
4
Database :
Academic Search Index
Journal :
Acta Crystallographica Section E: Crystallographic Communications
Publication Type :
Academic Journal
Accession number :
162929355
Full Text :
https://doi.org/10.1107/S2056989023001858