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Polyaniline-encapsulated quartz sand as an adsorbent composite for Orange G dye removal from aqueous solution: Experimental and computational study.
- Source :
-
Ceramics International . May2023:Part A, Vol. 49 Issue 9, p14120-14134. 15p. - Publication Year :
- 2023
-
Abstract
- The presented discovery provides a long-term strategy for successfully utilizing quartz sand (QS) as a low-cost, efficient, and environmentally friendly adsorbent. To improve the adsorption capacity and efficiency, a new chemical strategy was used to coat the QS particles with polyaniline (PANI), creating a hybrid material composite (QS@PANI). The prepared composite's ability to effectively remove Orange G dye (OG) from aqueous solutions was investigated through a series of batch adsorption experiments. The highest removal efficiency was due to the synergistic effect of the QS and the PANI, which favors electrostatic interaction, π-π interaction, and hydrogen bonding due to the nitrogen atoms in their conjugated chains. Adsorption kinetics were described by the pseudo-second-order, and Elovich models, while equilibrium capacity was described by the Langmuir adsorption model. Interestingly, after six repeated cycles, the composites unveiled a high removal proficiency >82% at different pH (2–8) of the solution and possessed an excellent adsorptive property, providing a cost-effective material for decolorization applications. Density functional theory (DFT) calculations and molecular dynamics simulations were utilized to elucidate the adsorption mechanism. The results showed that Orange G adsorption on QS@PANI occurs via a physisorption process. This research not only provided a structure-function relationship for PANI-QS organic-inorganic composite material assemblies, but it also provided an encouraging framework for the long-term advancement of water purification technology. [Display omitted] [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 02728842
- Volume :
- 49
- Issue :
- 9
- Database :
- Academic Search Index
- Journal :
- Ceramics International
- Publication Type :
- Academic Journal
- Accession number :
- 162705490
- Full Text :
- https://doi.org/10.1016/j.ceramint.2022.12.293