Back to Search
Start Over
Cooperative dihydrogen activation at a Na(I)2/Mg(I)2 ensemble.
- Source :
-
Chemical Communications . 4/4/2023, Vol. 59 Issue 26, p3846-3849. 4p. - Publication Year :
- 2023
-
Abstract
- [{SiNDipp}MgNa]2 ({SiNDipp} = {CH2SiMe2N(Dipp)}2; Dipp = 2,6-i-Pr2C6H3) reacts directly with H2 to provide a heterobimetallic hydride. Although the transformation is complicated by the simultaneous disproportionation of magnesium, computational density functional theory (DFT) studies suggest that this reactivity is initiated by orbitally-constrained and interactions between the frontier MOs of both H2 and the tetrametallic core of [{SiNDipp}MgNa]2. [ABSTRACT FROM AUTHOR]
- Subjects :
- *DENSITY functional theory
*MAGNESIUM
*MAGNESIUM hydride
Subjects
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 59
- Issue :
- 26
- Database :
- Academic Search Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 162698472
- Full Text :
- https://doi.org/10.1039/d3cc00710c