Stratified and gradient films by evaporation-induced stratification of bimodal latexes. Potential of confocal and scanning electron microscopy for compositional depth profiling.

In the field of bimodal latex film's formation, finding methods to quantify particle concentration profiles within the film thickness is a challenge. Herein the advantages and limitations of confocal fluorescence microscopy (CFM) and scanning electron microscopy (SEM) are presented. Films are prepared from a bimodal fluorescent acrylic mixture of large non-deformable particles and small deformable particles having high Péclet numbers. A fixed volume fraction of large particles (Φ L) in the dispersion is used with increasing volume fractions of small particles latex (Φ S). At low Φ S , a surface stratification of large particles occurs with thicknesses up to several micrometers, allowing detection by both CFM and SEM. Small particles form a stratified surface layer above a threshold Φ S value. Its thickness of less than 500 nm is evidenced only by SEM due to the resolution limit of the confocal scan. SEM is also able to reveal concentration gradients of large particles below the "small-on-top" stratified layer. [Display omitted] • A low enough vol. fraction in small particles induces a large-on-top stratification. • A critical vol. fraction in small particles induces a small-on-top stratification. • Small-on-top stratified structure is too thin to be resolved by confocal microscopy. • Confocal microscopy evidences large-on-top stratified layer at micrometer-scale. • SEM observations of film cross-sections reveal stratified and gradient structures. [ABSTRACT FROM AUTHOR]