Back to Search
Start Over
Mechanochemical Synthesized CaO/ZnCo 2 O 4 Nanocomposites for Biodiesel Production.
- Source :
-
Catalysts (2073-4344) . Feb2023, Vol. 13 Issue 2, p398. 18p. - Publication Year :
- 2023
-
Abstract
- Biodiesel has been recognized as an environmentally friendly, renewable alternative to fossil fuels. In this work, CaO/ZnCo2O4 nanocomposites were successfully synthesized via simple mechanochemical reaction between ZnCo2O4 and CaO powders by varying the CaO loading from 5 to 20 wt.%. The synthesized materials were found to be highly efficient heterogeneous catalysts for transesterification of tributyrin with methanol to produce biodiesel. The nanocomposite, which contained 20 wt.% CaO and 80 wt.% ZnCo2O4 (CaO/ZnCo2O4-20), exhibited superior and stable transesterification activity (98% conversion) under optimized reaction conditions (1:12 TBT to methanol molar ratio, 5 wt.% catalyst and 180 min. reaction time). The experimental results revealed that the reaction mechanism on the CaO/ZnCo2O4 composite followed pseudo first-order kinetics. The physicochemical characteristics of the synthesized nanocomposites were measured using X-ray diffraction (XRD), high resolution transmission electron microscopy (HRTEM), Fourier-transformed infrared spectroscopy (FTIR), X-ray photoelectron spectrometer (XPS), N2-physisorption, and CO2- temperature-programmed desorption (CO2-TPD) techniques. The results indicated the existence of coalescence between the CaO and ZnCo2O4 particles, Additionally, the CaO/ZnCo2O4-20 catalyst was found to possess the greater number of highly basic sites and high porosity, which are the key factors affecting catalytic performance in transesterification reactions. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 20734344
- Volume :
- 13
- Issue :
- 2
- Database :
- Academic Search Index
- Journal :
- Catalysts (2073-4344)
- Publication Type :
- Academic Journal
- Accession number :
- 162086249
- Full Text :
- https://doi.org/10.3390/catal13020398