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Structural insight into the magnesium borohydride – ethylenediamine solid-state Mg-ion electrolyte system.
- Source :
-
Dalton Transactions: An International Journal of Inorganic Chemistry . 2/28/2023, Vol. 52 Issue 8, p2404-2411. 8p. - Publication Year :
- 2023
-
Abstract
- A highly complex crystal structure of stoichiometric Mg5(en)6(BH4)10 was solved from single crystal synchrotron X-ray diffraction and confirmed by neutron powder diffraction (NPD) on isotopically substituted Mg(en)1.2(11BD4)2. We highlight the role of the amorphous Mg(BH4)2 in the reactivity of the Mg(BH4)2-en system and characterized a previously overlooked phase, Mg(en)2(BH4)2. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 14779226
- Volume :
- 52
- Issue :
- 8
- Database :
- Academic Search Index
- Journal :
- Dalton Transactions: An International Journal of Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 162011757
- Full Text :
- https://doi.org/10.1039/d2dt03567g