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Composition, depiction, antibacterial, antioxidant, and cytotoxicity activities studies of a new nano-sized binuclear metal (II) Schiff base complexes.

Authors :
Abd, Suha Sahab
Alkam, Hiyam Hadi
Al-Shemary, Rehab Kadhim Raheem
Source :
AIP Conference Proceedings. 2023, Vol. 2414 Issue 1, p1-13. 13p.
Publication Year :
2023

Abstract

In the current contribution, a novel binuclear nickel(II) and zinc(II) complexes were prepared from a hexadentate ligand prepared via condensation of 3,3'-Bipyridine-6,6'-dicarbaldehyde, 2-amino-5-chlorobenzaldehyde and 2-Aminophenol.The symmetric ligand sediment 2,2'-[3,3'-bipyridine]-6,6'-diylbis(methaneylylidene)bis (azaneylylidene) bis(5-chloro-2,1- phenylene) bis(methaneylylidene)bis(azaneylylidene)diphenol and its metal complexes were illustrated utilizing various techniques of physicochemical containing magnetic moment, analytical analysis and spectroscopy of mass, IR, 13C and 1H NMR, TGA and UV-Vis. The particles of MO Nanoscale were created from the labeled complex applying the ways of pyrolysis and utilizing methods of XRD, FT-IR, and FE-SEM, that specified close compatibility with the typical pattern for nanoparticles of NiO, ZnO and appeared the reasonable size in the nano reign (30 nm). The DNA interaction of these complexes was examined by applying viscosity measures, spectra of electronic and electrophoresis of gel. The in vitro antibacterial efficiencies of the compounds were screened versus bacteria such as Staphylococcus, Fecal enterococci, Enterococcus facials, Pseudomonas aeruginosa. All the metal complexes offered powerful bacterial efficiencies than the ligand. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
0094243X
Volume :
2414
Issue :
1
Database :
Academic Search Index
Journal :
AIP Conference Proceedings
Publication Type :
Conference
Accession number :
161845818
Full Text :
https://doi.org/10.1063/5.0121776