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Reactions of Benzenesulfonic Acid with Certain Tolyl Derivatives of Antimony.
- Source :
-
Russian Journal of General Chemistry . Dec2022, Vol. 92 Issue 12, p2676-2681. 6p. - Publication Year :
- 2022
-
Abstract
- Tetra(para-tolyl)antimony benzenesulfonate of the monoclinic modification was synthesized by the reaction between equimolar amounts of benzenesulfonic acid and antimony tolyl derivatives para-Tol4SbХ [X = Br, ONCHCH=CHPh, OС(O)CH2OС6H3Cl2-2,4] in a water-acetone solution. Carrying out these reactions in a benzene solution leads to the formation of tetra(para-tolyl)antimony benzenesulfonate of the rhombic modification. The structure of the obtained compounds, in which antimony atoms have a distorted trigonal-bipyramidal coordination with electronegative substituents in axial positions, was established by X-ray diffraction analysis. [ABSTRACT FROM AUTHOR]
- Subjects :
- *BENZENESULFONIC acid
*ANTIMONY
*X-ray diffraction
Subjects
Details
- Language :
- English
- ISSN :
- 10703632
- Volume :
- 92
- Issue :
- 12
- Database :
- Academic Search Index
- Journal :
- Russian Journal of General Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 161769075
- Full Text :
- https://doi.org/10.1134/S1070363222120179