Evaluating the performance of a Picarro G2207-i analyser for high-precision atmospheric O2 measurements.

Fluxes of oxygen (O 2) and carbon dioxide (CO 2) in and out of the atmosphere are strongly coupled for terrestrial biospheric exchange processes and fossil fuel combustion but are uncoupled for oceanic air–sea gas exchange. High-precision measurements of both species can therefore provide constraints on the carbon cycle and can be used to quantify fossil fuel CO 2 (ffCO 2) emission estimates. In the case of O 2 , however, due to its large atmospheric mole fraction (∼20.9 %) it is very challenging to measure small variations to the degree of precision and accuracy required for these applications. We have tested an atmospheric O 2 analyser based on the principle of cavity ring-down spectroscopy (Picarro Inc., model G2207- i), both in the laboratory and at the Weybourne Atmospheric Observatory (WAO) field station in the UK, in comparison to well-established, pre-existing atmospheric O 2 and CO 2 measurement systems. In laboratory tests analysing dry air in high-pressure cylinders, we found that the best precision was achieved with 30 min averaging and was ±0.5 ppm (∼±2.4 per meg). Also from continuous measurements from a cylinder of dry air, we found the 24 h peak-to-peak range of hourly averaged values to be 1.2 ppm (∼5.8 per meg). These results are close to atmospheric O 2 compatibility goals as set by the UN World Meteorological Organization. However, from measurements of ambient air conducted at WAO we found that the built-in water correction of the G2207- i does not sufficiently correct for the influence of water vapour on the O 2 mole fraction. When sample air was dried and a 5-hourly baseline correction with a reference gas cylinder was employed, the G2207- i 's results showed an average difference from the established O 2 analyser of 13.6±7.5 per meg (over 2 weeks of continuous measurements). Over the same period, based on measurements of a so-called "target tank", analysed for 12 min every 7 h, we calculated a repeatability of ±5.7±5.6 per meg and a compatibility of ±10.0±6.7 per meg for the G2207- i. To further examine the G2207- i 's performance in real-world applications we used ambient air measurements of O 2 together with concurrent CO 2 measurements to calculate ffCO 2. Due to the imprecision of the G2207- i , the ffCO 2 calculated showed large differences from that calculated from the established measurement system and had a large uncertainty of ±13.0 ppm, which was roughly double that from the established system (±5.8 ppm). [ABSTRACT FROM AUTHOR]