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Intramolecular Friedel–Crafts alkylation by electrochemical carbenium ion generation.
- Source :
-
Chemistry of Heterocyclic Compounds . Dec2022, Vol. 58 Issue 12, p732-736. 5p. - Publication Year :
- 2022
-
Abstract
- Electrochemical activation of trialkylstannylmethyl group as an electroauxiliary for carbenium ion generation enables the intramolecular Friedel–Crafts alkylation. Electrochemical activation of stannylmethyl group forms carbenium ion which can be trapped by intramolecular (het)aromatic nucleophiles for the formation of new 6-membered cycles. [ABSTRACT FROM AUTHOR]
- Subjects :
- *CARBENIUM ions
*ALKYLATION
*NUCLEOPHILES
Subjects
Details
- Language :
- English
- ISSN :
- 00093122
- Volume :
- 58
- Issue :
- 12
- Database :
- Academic Search Index
- Journal :
- Chemistry of Heterocyclic Compounds
- Publication Type :
- Academic Journal
- Accession number :
- 161302499
- Full Text :
- https://doi.org/10.1007/s10593-023-03150-w