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Construction of a MOF‐Supported Palladium Catalyst via Metal Metathesis.
- Source :
-
Chemistry - An Asian Journal . 1/3/2023, Vol. 18 Issue 1, p1-7. 7p. - Publication Year :
- 2023
-
Abstract
- A new MOF‐supported heterogeneous palladium catalyst Pd/NBB‐1 has been synthesized successfully through the effective metal metathesis between Pd(CF3COO)2 and NBB‐1. NBB‐1 is a two‐dimensional zinc metal‐organic framework constructed from 2‐aminoterephthalate (NH2−H2BDC) and 2,2′‐bipyridine‐5‐carboxylate (HBPC) by solvothermal method. The replacement efficiency of Pd(II) to Zn(II) is up to 72% after only 24 hours, which is beneficial to the catalytic application. Pd/NBB‐1 with a low loading of 2 mol% works efficiently in the 1,4‐addition reaction of arylboronic acids with α,β‐unsaturated ketones in air, and its catalytic activity keeps unchanged after 3 reaction cycles. This work provides a new strategy to effectively prepare supported noble metal/MOF catalysts, which would further increase the practical applications of metal‐organic frameworks. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 18614728
- Volume :
- 18
- Issue :
- 1
- Database :
- Academic Search Index
- Journal :
- Chemistry - An Asian Journal
- Publication Type :
- Academic Journal
- Accession number :
- 161113766
- Full Text :
- https://doi.org/10.1002/asia.202201096