STUDY OF THE STRUCTURE OF Ag(I) SOLVATE COMPLEXES BY MEANS OF POLYOXOMETALATES: CRYSTALLIZATION FROM THE AgNO3/(Bu4N)4[β-Mo8O26]/DMF SYSTEM. REVIEW.

The review summarizes information about the known Ag+ solvate complexes isolated and structurally characterized as adducts and/or salts with polyoxometalates. The AgNO3/(Bu4N)4[β-Mo8O26]/N,N-dimethylformamide (DMF) system along with the complexes isolated for the first time are considered in detail: (Bu4N)4[Ag2(NO3)2Mo8O26]; (Bu4N)2n[Ag1.8(MoO2)0.2Mo8O26]n; (Bu4N)4[Ag2(DMF)4Mo8O26] [Ag2(DMF)2Mo8O26]; (Bu4N)4[Ag2(DMF)4Mo8O26][Ag2(DMF)2Mo8O26]·0.25DMF. [ABSTRACT FROM AUTHOR]