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AIEE active stilbene based fluorescent sensor with red-shifted emission for vapor phase detection of nitrobenzene and moisture sensing.
- Source :
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Journal of Photochemistry & Photobiology A: Chemistry . Mar2023, Vol. 437, pN.PAG-N.PAG. 1p. - Publication Year :
- 2023
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Abstract
- [Display omitted] • Stilbene-based sensor 1 was synthesized and characterized. • The AIEE active fluorescent sensor displayed a significant red shift that was attributed to J -aggregates formation. • Sensor 1 was highly selective and sensitive for solution and vapor phase detection of nitrobenzene (NB). • Sensor 1 was employed for the detection of moisture in organic solvent. • Sensor was used for contact mode identification and rapid detection of nitrobenzene in real samples. • DFT studies were performed to investigate mechanism and to further evaluate type of non-covalent interactions. A unique π-electron rich stilbene-based sensor with significantly enhanced red-shifted fluorescence emission has been synthesized via a Mizoroki-Heck cross-coupling reaction. The strong fluorescence properties of stilbene derivative as a potential fluorescent sensor have been investigated for sensitive and selective detection of hazardous and threatening nitrobenzene (NB) in both solution and vapor phase. The fluorescence emission intensity of stilbene sensor 1 at 474 nm was quenched upon interaction with NB. The fluorescence quenching was attributed to the combined effect of dominant smaller and adjustable size of NB and photo-induced electron transfer (PET) process. Stilbene sensor 1 is the first active bathochromic shifted fluorescent sensor with AIEE property was developed for both solution and vapor phase detection of NB. Possible interactions of stilbene sensor 1 with NB was evaluated by UV– vis., fluorescence, density functional theory (DFT) calculations, and 1H NMR titration experiment. Additionally, non-covalent interaction (NCI), Frontier molecular orbitals (FMOs) and interaction energy were studied by using Gaussian 09 software. Moreover, test strips were fabricated to accomplish contact mode detection of NB. Further, stilbene sensor 1 was successfully applied for trace detection of NB in real water samples. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 10106030
- Volume :
- 437
- Database :
- Academic Search Index
- Journal :
- Journal of Photochemistry & Photobiology A: Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 160961995
- Full Text :
- https://doi.org/10.1016/j.jphotochem.2022.114459