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Separator modification of lithium-sulfur batteries based on Ni-Zn bimetallic MOF derived magnetic porous Ni-C composites.
- Source :
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Journal of Alloys & Compounds . Feb2023:Part 2, Vol. 935, pN.PAG-N.PAG. 1p. - Publication Year :
- 2023
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Abstract
- Because of its high theoretical specific capacity, lithium-sulfur batteries are regarded as one of the most promising secondary batteries. However, there are still a series of problems, which seriously affect the commercial application of lithium-sulfur batteries. Therefore, a magnetic porous carbon material was developed in this work for the modification of lithium-sulfur battery separators, which may reduce the shuttle effect of polysulfides and increase its electrochemical performances. The solvothermal preparation of Ni-Zn bimetallic MOF precursors was followed by a high-temperature carbonization in nitrogen environment to sublimate Zn ions and produce porous structures, achieving Ni@C(Zn) composite. In order to improve the electrochemical performances of lithium-sulfur batteries, the Ni@C(Zn) composite was coated on one side of the polyethylene (PE) separator. Ni@C(Zn) composite displays good physisorption and chemisorption properties, and it can also operate as a secondary current collector to promote the usage of active materials as well as inhibiting shuttle effect of polysulfides. By using Ni@C(Zn) coated PE separator, the initial discharge specific capacity of lithium sulfur battery is as high as 1278.6 mAh g−1 at a current density of 0.05 C when the S cathode is loaded with 3 mg cm−2 active materials. Furthermore, the discharge specific capacity in the first cycle at 0.5 C is 749.4 mAh g−1, which remains at 461 mAh g−1 after 500 long cycles, and the capacity retention rate is as high as 61.5%. Even when the S loading is as high as 5 mg cm−2, it can still experience a stable cycle of 100 cycles at 0.2 C. • Ni@C(Zn) composite was derived by bimetallic Ni-Zn MOFs. • Ni@C(Zn) composite was used as separator modification layer of lithium sulfur battery. • larger specific surface area and higher porosity can better block the shuttle of polysulfides. • Ni@C(Zn) composites have good catalytic effect which can promote the redox conversion of polysulfides. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 09258388
- Volume :
- 935
- Database :
- Academic Search Index
- Journal :
- Journal of Alloys & Compounds
- Publication Type :
- Academic Journal
- Accession number :
- 160535067
- Full Text :
- https://doi.org/10.1016/j.jallcom.2022.168066