Microcrack healing in single-crystal cubic zirconia by thermal annealing.

Thermally healed Vickers microcracks perpendicular to (001) surface of cubic zirconia single crystals were investigated mainly with scanning transmission electron microscopy. The orientational relationship of areas containing healed microcracks was completely restored to that of the original single crystal, but a row of pores corresponding to the unhealed state remained where the original microcrack was located. Isolated pore formation proceeded from dislocation recovery via heat treatment, which brought the inner surfaces of the microcrack into contact, followed by diffusion bonding via surface diffusion. Once isolated pores were formed, the total pore volume did not significantly change by increasing the healing temperature, although pore sizes increased and the number of pores decreased. Ostwald ripening became pronounced in pore microstructure evolution when pore elimination was dominated by lattice diffusion after complete crystallographic restoration to a single crystal. • Healing of microcracking in single crystal cubic zirconia investigated. • Microcrack partially healed by annealing at 1250–1400 °C for 10 min. • Crystallographic orientation was completely restored to original one after healing. • A row of pores with plate-like hexagonal and rhombic shapes remained. • Dislocation recovery closes crack, followed by diffusion bonding by surface diffusion. [ABSTRACT FROM AUTHOR]