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Orthoamide und Iminiumsalze, CVIIa. 4-Sulfonylierte- und 4-phosphorylierte sowie 4-isocyansubstituierte-1,1-Bis(dimethylamino)-1,3-butadiene aus Sulfonen, (Alkyl)phosphonsäureestern sowie Isocyanessigsäureester und Orthoamid-Derivaten von Alkincarbonsäuren

Authors :
Kantlehner, Willi
Vettel, Markus
Lehmann, Hansjörg
Frey, Wolfgang
Source :
Zeitschrift für Naturforschung B: A Journal of Chemical Sciences. Dec2022, Vol. 77 Issue 11/12, p809-829. 21p.
Publication Year :
2022

Abstract

The article describes various chemical reactions in which orthoamides are reacted with other compounds. New compounds are synthesized, such as vinylogous guanidinium bromides and vinylogous guanidinium tetraphenylborates. Ketenimines are also synthesized from orthoamides and phosphonic acid esters. The structure of the ketenimines is described by polar resonance structures. Information is also provided on the yields and properties of the resulting compounds. Further investigations into the reactions and the resulting compounds are encouraged. [Extracted from the article]

Details

Language :
German
ISSN :
09320776
Volume :
77
Issue :
11/12
Database :
Academic Search Index
Journal :
Zeitschrift für Naturforschung B: A Journal of Chemical Sciences
Publication Type :
Academic Journal
Accession number :
160425827
Full Text :
https://doi.org/10.1515/znb-2022-0051