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Co isomorphic substitution for Cu-based metal organic framework based on electronic structure modulation boosts Fenton-like process.
- Source :
-
Separation & Purification Technology . Feb2023:Part A, Vol. 306, pN.PAG-N.PAG. 1p. - Publication Year :
- 2023
-
Abstract
- • CuCo-based MOF was prepared via a facile solvothermal method. • CuCo-MOF displays excellent activity for NIM degradation. • The synergy between the Cu-Co dual active centers enhanced the activation of PMS. • The NIM reaction site was revealed and its degradation path was proposed. • Cu and Co dual active sites to favor Cu and Co-PMS adsorption and charge transfer. Regulation of active sites is of significant importance for boosting the catalytic properties of metal–organic frameworks (MOF). Herein, we developed a one-pot strategy to construct bimetallic organic frameworks with Cu-Co double sites (CuCo-MOF) for peroxymonosulfate (PMS) activation. CuCo-MOF exhibits excellent active oxidation capacity, enabling complete removal of NIM within 25 min (0.227 min−1). Its NIM degradation rate was 7.3 and 2.4 times higher than that of Cu-MOF and Co-MOF, respectively. The theoretical simulations unravel that doping Co into the lattice structure of Cu-MOF promotes electron transfer from the electron-rich region (benzene ring) to the electron-deficient regions around metal sites, which facilitated the optimization of the adsorption energy for PMS activation and boosted the breakage of O O bond in PMS. According to LC-MS analysis and DFT calculation, the NIM degradation pathways were proposed, and its degradation intermediates were conducted for toxicity evaluation. The findings, revealing the synergistic effect of bimetals, open a new avenue for the rational design of highly efficient MOF-based Fenton-like catalysts. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 13835866
- Volume :
- 306
- Database :
- Academic Search Index
- Journal :
- Separation & Purification Technology
- Publication Type :
- Academic Journal
- Accession number :
- 160399013
- Full Text :
- https://doi.org/10.1016/j.seppur.2022.122526