National-scale spatial variations of soil phosphorus retention capacity in Brazil.

Phosphorus (P) retention capacity of soils directly affects the management of phosphate fertilization, and has economic and environmental importance. Brazil has expressive agricultural production and high edaphoclimatic variability; still, the detailed spatial distribution of P retention capacity is not known. Thus, machine learning models were created to estimate the P retention capacity of soils at superficial horizons using the variables: clay content, sand content, soil organic matter, pH, base saturation. The four best models were combined to create an ensemble (a combination of models), which was applied in a dataset (5524 samples) that comprises a sample data from the entire Brazilian territory. The ensemble was used to build a map of P retention capacity. Most of the country presented soils with medium P retention (40–60%), and large areas with very high retention capacity were found in the south of Brazil, a subtropical region mostly associated with clayey soils. High P retention was observed for Histosols, probably related to humic-Al(Fe) complexes. Nitisol, Ferralsol, Gleysol and Cambisol classes presented high P retention, especially for clayey soils with qualifiers related to bases/weathering (Dystric) and organic matter (Umbric and Humic). The correlation between Fe oxide minerals and P retention varied with soil color and drainage conditions mainly associated to redoximorphic reactions; the same was not observed for Al oxide minerals. This pioneer study revealed the distribution of P retention capacity across different soil classes in Brazil, which can help to define land use suitability and soil P management strategies that ensure profitable agricultural exploration. [Display omitted] • In 34% of the country, soils had P retention capacity framed as Low and 22% as High. • The Histosol class presenting soils with elevated P retention capacity (>60%). • For mineral soils, the highlighted classes were Nitisol, Ferralsol, Gleysol and Cambisol. • Soil color and drainage conditions had little effect on soil P retention capacity. [ABSTRACT FROM AUTHOR]