Back to Search
Start Over
125Te NMR study of the bulk of topological insulators Bi2Te3 and Sb2Te3.
- Source :
-
Zeitschrift für Anorganische und Allgemeine Chemie . Nov2022, Vol. 648 Issue 21, p1-6. 6p. - Publication Year :
- 2022
-
Abstract
- The narrow band gap semiconductors Bi2Te3 and Sb2Te3 are well known for their room temperature thermoelectric performance. Recently, they were shown to serve as model systems of three‐dimensional topological insulators with a bulk band gap and very robust, spin‐resolved surface states due to a special band inversion in their periodic bulk. Evidently, it is of interest to investigate the special surface states with a local probe like nuclear magnetic resonance (NMR). However, especially the bulk NMR of these materials shows peculiar and rather unexpected phenomena, e. g., a magnetic field induced deformation of the local charge symmetry and excessive line broadening due to a special internuclear coupling. Here we report a comprehensive account of the room temperature NMR properties of the spin‐1/2 nucleus 125Te of single crystalline Bi2Te3 and Sb2Te3. This includes a very unusual spin‐lattice relaxation that seems not to be reflected in the NMR shift, as well as an exchange enhanced NMR line broadening. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00442313
- Volume :
- 648
- Issue :
- 21
- Database :
- Academic Search Index
- Journal :
- Zeitschrift für Anorganische und Allgemeine Chemie
- Publication Type :
- Academic Journal
- Accession number :
- 160232251
- Full Text :
- https://doi.org/10.1002/zaac.202200208