Fluorescent Janus ring siloxanes for detection of Au(III) and l-cysteine.

Two new all- cis pyrene-substituted cyclic tetrasiloxanes (JR-01 and JR-02) are synthesized and studied as selective metal ion sensors. Both compounds exhibit solvent- and concentration-dependent excimer fluorescence emission at 482 nm. They also show highly selective fluorescence quenching by Au(III) ion with detection limits of 0.9 and 0.8 μM for JR-01 and JR-02 , respectively. Data from the Stern-Volmer's plots at various temperatures, zetasizers, NMR, and UV–Vis spectroscopy indicate a plausible mechanism involving the formation of a non-emissive Au(III) complex. An application of JR-01 as Au(III) sensor in real water samples reveals a good sensing efficiency which is comparable to the analysis result from ICP-QMS. In addition, when an excess amount of l -cysteine is added to the JR-01 /Au(III) mixture, the fluorescence signal is restored and the 1H NMR data suggests that JR-01 remains intact. As an extension of this study, we successfully demonstrate the detection of l -cysteine by fluorescence turn-on process using the JR-01 /Au(III) mixture with a detection limit of 14.0 μM. • Two new cyclic tetrasiloxanes are synthesized as selective Au(III) sensors. • The sensing mechanism involves the formation of a non-emissive complex. • The Au(III) complex can be used as a turn-on sensor for l -cysteine. [ABSTRACT FROM AUTHOR]