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Pharmaceutical pollutants adsorption onto activated carbon: isotherm, kinetic investigations and DFT modeling approaches.
- Source :
-
Comptes Rendus Chimie . 2022 Sepcial Issue, Vol. 25, p9-25. 17p. - Publication Year :
- 2022
-
Abstract
- In this work, significant interest has been focused on removing pharmaceutical pollutants, i.e., oxytetracycline (OTC), which was studied through adsorption onto activated carbon (ACT) produced from households or agricultural wastes under various experimental conditions. The physicochemical properties of the produced carbon were investigated using multiple techniques. The characterization analysis highlighted an essential concentration of surface functional groups and a very developed porous structure. The adsorption process onto activated carbon occurswith a high yield at a large range of pH values varying between 4 and 8 at an optimumcontact time of 2 h. It was established that the pseudo-second-order kinetic model fitted well OTC adsorption onto ACT. Moreover, the adsorption isothermdata showed that the pollutant removal process followed the Langmuirmodel with high regression coefficients (R²) values and important adsorption efficiency of 80% for 100 mg.L-1 of OTC. The displayed results consequently, the use of ACT as an adsorbent could be considered an efficient, sustainable, and low-cost alternative for pharmaceuticals-loaded wastewater treatment. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 16310748
- Volume :
- 25
- Database :
- Academic Search Index
- Journal :
- Comptes Rendus Chimie
- Publication Type :
- Academic Journal
- Accession number :
- 160062930
- Full Text :
- https://doi.org/10.5802/crchim.161