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Hierarchical conducting polymer coated conjugated polyimide anode towards durable lithium-ion batteries.
- Source :
-
Journal of Power Sources . Dec2022, Vol. 552, pN.PAG-N.PAG. 1p. - Publication Year :
- 2022
-
Abstract
- Organic polymer materials attract lots of attention as promising anode materials for lithium ion batteries (LIBs) due to the superior lithium ion storage capability and low cost. However, the inherent insulativity of the polymer anodes results in the unsatisfactory electrochemical performance. Herein, we design and construct a hierarchical flowers-like polyaniline-coated (PANI) pyromellitic dianhydride-based polyimide (PPI) composite (PANI-PPI-9). Benefiting from the core-shell structure, the PPI presents an improved electrochemical performance, especially the remarkable cycling life (503 mAh g−1 at 1.5 A g−1 after 2400 cycles). Ex-situ characterizations and kinetics analyses also verify that the PANI shell serves as the electronic transport highway without obstructing the Li storage of PPI. This work highlights the potential application of the multifarious polymer-based composite electrodes for the lithium ion batteries. • The structure construct strategy to design and prepare the PANI-coated PPI micron flowers. • Aromatic rings in the polyimide provide a large number of lithium storage sites. • The PANI-PPI-9 exhibits improved long-cycling and rate performance. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 03787753
- Volume :
- 552
- Database :
- Academic Search Index
- Journal :
- Journal of Power Sources
- Publication Type :
- Academic Journal
- Accession number :
- 159926461
- Full Text :
- https://doi.org/10.1016/j.jpowsour.2022.232226