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Photocatalytic performances and mechanisms of two coordination polymers based on rigid tricarboxylate.
- Source :
-
Journal of Solid State Chemistry . Dec2022, Vol. 316, pN.PAG-N.PAG. 1p. - Publication Year :
- 2022
-
Abstract
- In this work two new coordination polymers (CPs) with formulas [Zn 2 (Cl)(BTC)(bmb) 2 ] (1) and [Cd 2 (H 2 O) 2 (BTC) 2 ·H 2 bmb·6H 2 O] (2) (bmb=1,4-bis(2-methylimidazol-1-yl)butane and H 3 BTC = 1,3,5-benzenetricarboxylic acid), have been prepared and characterized by various spectroscopic data. The single crystal X-ray data suggests that 1 comprises a 2D layered network and 2 has a 3D porous framework with pcu -type topology. The photocatalytic properties revealed that 2 could successfully degrade organic dyes such as Rhodamine B (Rh B), methylene orange (MO), and methylene blue (MB). Further, the trapping experiment established the active species in the photodegradation process. [Display omitted] • Two new MOFs were synthesized using mixed strategy. • The two MOFs were modulated by synthesized temperature. • Photocatalytic capability was demonstrated for the MOFs. • The photodegradation process was estimated by trapping experiment. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00224596
- Volume :
- 316
- Database :
- Academic Search Index
- Journal :
- Journal of Solid State Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 159907787
- Full Text :
- https://doi.org/10.1016/j.jssc.2022.123602