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Interface effect in MIL-53(Fe)/metal-phenolic network (Ni, Co, and Mn) nanoarchitectures for efficient oxygen evolution reaction.
- Source :
-
Applied Surface Science . Jan2023, Vol. 608, pN.PAG-N.PAG. 1p. - Publication Year :
- 2023
-
Abstract
- [Display omitted] • MIL-53(Fe)/metal (Ni, Co, Mn)-phenolic network nanoarchitectures were fabricated for OER. • MIL-53(Fe)/Ni-phenolic network nanoarchitectures revealed the best electrochemical performance due to interface effect. • This work supplied an efficient approach for water splitting. The interface nature of composite catalysts affected drastically the oxygen evolution reaction (OER) behavior. In this paper, nanoarchitecture consisted of Fe-based metal–organic frameworks (MIL-53) and metal-phenolic networks were created. Metal (Mn2+, Co2+, and Ni2+) phenolic networks were assembled on the surface of MIL-53 to form heterostructures. Among them, MIL-53(Fe)/Ni-phenolic network nanoarchitectures revealed the best electrochemical performance. The existence of MIL-53 enhanced the adsorption ability for OH− in the nanoarchitectures. The electron transfer between MIL-53 and Ni-phenolic networks adjusted the filling degree of e g orbitals to optimize the bonding strength between Fe3+/Ni2+ and oxygen intermediate species. MIL-53/Ni-phenolic networks nanoarchitectures exhibited well OER performance with a potential of 282 mV at 10 mA cm−2. This work provided an efficient insight into the structure-properties relation of a promising heterostructure catalyst for water splitting. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 01694332
- Volume :
- 608
- Database :
- Academic Search Index
- Journal :
- Applied Surface Science
- Publication Type :
- Academic Journal
- Accession number :
- 159819761
- Full Text :
- https://doi.org/10.1016/j.apsusc.2022.155184