Back to Search
Start Over
Preparation of hierarchically floral ZIF-8 derived carbon@polyaniline@Ni/Al layered double hydroxides composite with outstanding removal phenomenon for saccharin.
- Source :
-
Chemical Engineering Journal . Dec2022:Part 3, Vol. 450, pN.PAG-N.PAG. 1p. - Publication Year :
- 2022
-
Abstract
- [Display omitted] • Hierarchically floral ZC@PANI@NiAl-LDH composite was prepared and characterized. • Experiment and theoretical calculations interpret the adsorption mechanisms. • LOL-π, π electron density, and IRI-π isosurface indicate the π-π interaction. • IGMH and Hirshfeld surface analyses reveal the hydrogen bond interaction. • Saccharin and NiAl-LDH act as the H-bond acceptor and donor, respectively. In this work, ZIF-8 derived carbon@polyaniline@Ni/Al layered double hydroxides (denoted as ZC@PANI@NiAl-LDH) composite has been successfully designed via the facial synthesis of the ZIF-8, followed by high-temperature pyrolysis, oxidative polymerization of polyaniline, and in-site growth of NiAl-layered double hydroxides. Meanwhile, the composite acts as an advanced adsorption material for the scavenging of saccharin from aqueous solutions. Moreover, benefiting from the unique three-dimensional (3D) hierarchically floral structure and various functional groups, the as-prepared ZC@PANI@NiAl-LDH composite presents a high adsorption capacity (498.5 mg/g) for saccharin, superior to other reported adsorbents. Besides, the ZC@PANI@NiAl-LDH possesses rapid adsorption kinetics and excellent reusability performance. Furthermore, Fourier transformed infrared spectroscopy (FT-IR) and X-ray photoelectron spectroscopy (XPS) analyses initially reveal the possible adsorption mechanism, including electrostatic interactions, π-π interactions, and hydrogen bonding. Quantum chemical theory calculations further indicate the above adsorption mechanism. Significantly, based on the Hirshfeld surface analyses, saccharin behaves as the H-bond acceptor, while the NiAl-LDH works as the H-bond donor. This work provides a feasible strategy to design advanced materials for practical wastewater treatment. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 13858947
- Volume :
- 450
- Database :
- Academic Search Index
- Journal :
- Chemical Engineering Journal
- Publication Type :
- Academic Journal
- Accession number :
- 159075376
- Full Text :
- https://doi.org/10.1016/j.cej.2022.138127