Enhanced visible light response of Ag/SnO2 nanostructure enables high-efficiency photocatalytic hydrogen evolution.

Construction of synergistic photocatalysis system is regarded as an important concept for effectively utilizing solar energy. Herein, Ag nanoparticles decorated SnO 2 flower-like structure is designed and fabricated to synergistically realize efficient hydrogen production from water splitting. According to the results of density functional theory simulations and corresponding experimental analyses, it is identified that interfacial charge coupling of composite system intrinsically facilitate the efficient interfacial charge migration and separation. Moreover, introducing Ag nanoparticles not only expands response range of incident light for SnO 2 through LSPR effect but also reduces the hydrogen adsorption free energy in the catalytic process. Eventually, contributed by the enhanced interaction between reactants and catalysts and optimized carrier behavior, Ag/SnO 2 exhibits a faster hydrogen production rate than SnO 2. The research method designed in this paper may provide a new idea for research of photocatalyst for photocatalytic hydrogen evolution. [Display omitted] • LSPR effect of Ag expands the incident light response range of SnO 2. • Introduction of Ag improves carrier migration environment and carrier separation efficiency. • Enhanced interaction between reactants and catalysts is achieved. • Ag/SnO 2 exhibits enhanced photocatalytic hydrogen evolution. [ABSTRACT FROM AUTHOR]