CHEMICAL CHARACTERIZATION AND MANUFACTUR)ING TECHNOLOGY OF SOME LUSTRE CERAMIC DISHES OF THE ABBASID PERIOD, NORTHERN EGYPT.

This paper studies some ceramic lustreware dishes with metallic glaze dating back to the Abbasid era (2-3rd century AH/8-9th AD) and preserved in Rashid archaeological stores. The samples were selected based on the diversity of textual and pictoral decorations including written words, plants, animals and geometric elements. The manufacturing process and mineral and chemical composition of the dishes have been subjected to several examination and analytical methods including stereo microscope, scanning electron microscope (SEM-EDX), X-ray diffraction (XRD), X-ray fluorescence (XRF), Fourier transform infrared (ATR-FTIR) spectroscopy and differential thermal analysis (DTA). The study revealed a heterogeneous distribution of the color grains on the surface of the dishes and nanoparticles of metallic silver/copper ranging between 50-100nm. The metal oxides of the silver nanoparticles appeared in high percentage compared to nano copper particles on the surface of the lustre metallic layer which fact accounts for the greenish brown color of the dishes. While Arabic gum was used for fixing the decorations, the lustre layer was fired at 500°C and the firing of the ceramic body varied between 700°C and 800°C. A treatment and maintenance plan is suggested to preserve the pieces from further damage owing to their high archaeological value. [ABSTRACT FROM AUTHOR]