Back to Search
Start Over
Regeneration and utilization of graphite from the spent lithium-ion batteries by modified low-temperature sulfuric acid roasting.
- Source :
-
Waste Management . Aug2022, Vol. 150, p30-38. 9p. - Publication Year :
- 2022
-
Abstract
- [Display omitted] • Modified low-temperature sulfated roasting is used to recycle spent graphite. • The purity of recycled graphite reached 99.55% and the recovery rate exceeds 94%. • Economical products Na 2 SO 4 and NaF can be obtained by treating wastewater and gas. • The valuable metal recovery rates are all over 99%. • The generated graphite shows excellent columbic efficiency and capacity retention. Recycling spent graphite in spent lithium-ion batteries (LIBs) is crucial for lacking high-quality graphite and environmental protection. Here, an environmentally friendly and economical modified method based on sulfate roasting was proposed to recycle spent graphite via low temperature roasting at 250 °C with sodium fluoride as an assistant additive. Recycling leads to graphite with a high purity of 99.55 % and chemical structures for energy storage. Batteries manufactured in regenerated graphite deliver a high initial charge capacity of 333.9 mAh/g with an initial columbic efficiency of 85.71% and excellent capacity retention of 91.2% after 400 cycles. In addition, the waste produced in the method could be well treated, and by-products 177 g of sodium sulfate would be collected per 1 kg spent graphite and NaF, equivalent to 78.95% of the added amount obtained through wastewater and exhaust gas, respectively. The regenerated sodium fluoride will be re-applied to the recovery spent graphite. The loop-closed method shows great promise for the industrial-scale recycling of spent graphite for energy storage applications. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 0956053X
- Volume :
- 150
- Database :
- Academic Search Index
- Journal :
- Waste Management
- Publication Type :
- Academic Journal
- Accession number :
- 158403238
- Full Text :
- https://doi.org/10.1016/j.wasman.2022.06.037