Investigation of PCBM/ZnO and C60/BCP-based electron transport layer for high-performance p-i-n perovskite solar cells.

The objective of this study was to comprehensively investigate and compare PCBM/ZnO and C 60 /BCP-based electron transport layers (ETLs) (well recognized as representative ETLs) between perovskite and metal electrode in perovskite solar cells (PeSCs) for high-performance p-i-n structure PeSCs. Their film characteristics and their effects on solar cell performances were studied. When PCBM/ZnO was used as ETL material, the PCE of PeSCs was 19.36 %, which was higher than the PCE of 17.10 % when C 60 /BCP was used possibly due to more efficient charge recombination reduction and charge extraction shown in PCBM/ZnO-based devices. However, in terms of stability (air, light-soaking, and heat), C 60 /BCP-based devices showed higher stability than PCBM/ZnO-based devices. • A higher PCE was obtained in PCBM/ZnO (19.36 %) than that of C 60 /BCP (17.10 %). • C 60 /BCP shows better stability than PCBM/ZnO. • The selection of an appropriate ETL is important in terms of stability and efficiency. [ABSTRACT FROM AUTHOR]